The Packing Group assigned will be II or III, according to the classification criteria for either Class 3 or Division 4.1, as appropriate, applied to the base material. b. B42 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105J. N7 The hazard class or division number of the material must be marked on the package in accordance with 172.302 of this subchapter. 181 When a package contains a combination of lithium batteries contained in equipment and lithium batteries packed with equipment, the following requirements apply: a. a. If the material has a flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this subchapter are applicable. 114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Division 1.4 Compatibility Group D (1.4D) if the following conditions are met: a. Additionally, the offeror must notify the carrier if the tank pressure rise exceeds 3 psig over any 24-hour period. Tables 1, 2, and 3 follow: 1 Flexible plastic (51H) Large Packagings are only authorized for use with flexible inner packagings. When portable tank instruction T75 is referenced in Column (7) of the 172.101 Table, the applicable refrigerated liquefied gases are authorized to be transported in portable tanks in accordance with the requirements of 178.277 of this subchapter. The material must be loaded dry. For transportation of new lighter design samples for examination and testing, see 173.308(b)(2). Orientation markings as described in 172.312(a)(2) are required when liquid hazardous materials may escape due to incorrect orientation. When a special provision specifies packaging or packaging requirements -, (1) The special provision is in addition to the standard requirements for all packagings prescribed in 173.24 of this subchapter and any other applicable packaging requirements in subparts A and B of part 173 of this subchapter; and. D. Class 5 materials The Office of the Federal Register publishes documents on behalf of Federal agencies but does not have any authority over their programs. W100 Non-bulk flexible, fibreboard or wooden packagings must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. "Published Edition". A11 For combination packagings, when metal inner packagings are permitted, only specification cylinders constructed of metals which are compatible with the hazardous material may be used. 22 If the hazardous material is in dispersion in organic liquid, the organic liquid must have a flash point above 50 C (122 F). Packagings of other material with a small amount of metal, for example metal closures or other metal fittings such as those mentioned in part 178 of this subchapter, are not considered metal packagings. b. Lithium batteries conforming to paragraph a. of this special provision must be assigned to UN Nos. 105 The word Agents may be used instead of Explosives when approved by the Associate Administrator. Alcoholic beverages containing more than 24 percent but not more than 70 percent alcohol by volume must be transported as materials in Packing Group III. Your Nuclear Attack Map for 2023 - mirasafety.com N73 Packagings consisting of outer wooden or fiberboard boxes with inner glass, metal or other strong containers; metal or fiber drums; kegs or barrels; or strong metal cans are authorized and need not conform to the requirements of part 178 of this subchapter. (2) To the extent a special provision imposes limitations or additional requirements on the packaging provisions set forth in column 8 of the 172.101 table, packagings must conform to the requirements of the special provision. This includes vehicles transported in a packaging. The temperature of the material at the time it is offered for transport and during transportation may not exceed 55 C (130 F). c. Each glass inner packaging is protected by a means of preventing puncture of the plastic bag (e.g., sleeves or cushioning) in the event of damage to the packaging (e.g., by crushing). 172.101 Hazardous Materials Table (HMT). 382 Packages containing toy plastic or paper caps for toy pistols described as UN0349, Articles, explosive, n.o.s. Effective January 1, 2014, for transportation domestically by highway or rail, this entry may only be used if the results of Test Series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. B85 Cargo tanks must be marked with the name of the lading in accordance with the requirements of 172.302(b). N4 For combination or composite packagings, glass inner packagings, other than ampoules, are not permitted. A9 For combination packagings, if plastic bags are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. 197 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). A34 Aerosols containing a corrosive liquid in Packing Group II charged with a gas are not permitted for transportation by aircraft. b. 12 In concentrations greater than 40 percent, this material has strong oxidizing properties and is capable of starting fires in contact with combustible materials. These entries include hybrid electric vehicles powered by a fuel cell engine, an internal combustion engine, and batteries. For transportation by aircraft, a telephone report in accordance with 171.15(a) is required if a fire, violent rupture, explosion or dangerous evolution of heat (i.e., an amount of heat sufficient to be dangerous to packaging or personal safety to include charring of packaging, melting of packaging, scorching of packaging, or other evidence) occurs as a direct result of a dry battery. B131 When transported by highway, rail, or cargo vessel, waste Paint and Paint related material (UN1263; PG II and PG III), when in plastic or metal inner packagings of not more than 26.5 L (7 gallons), are excepted from the marking requirements in 172.301(a) and (c) and the labeling requirements in 172.400(a), when further packed in the following specification and non-specification bulk outer packagings and under the following conditions: a. 62 Oxygen generators (see 171.8 of this subchapter) are not authorized for transportation under this entry. Symbol Meaning Which is the correct column for hazardous materials? A30 Ammonium permanganate is not authorized for transportation on aircraft. 391 Except for articles being transported by motor vehicle as a material of trade in accordance with 173.6 of this subchapter, articles containing hazardous materials of Division 2.3, or Division 4.2, or Division 4.3, or Division 5.1, or Division 5.2, or Division 6.1 (substances with an inhalation toxicity of Packing Group I) and articles containing more than one of the following hazards: (1) Gases of Class 2; (2) Liquid desensitized explosives of Class 3; or (3) Self-reactive substances and solid desensitized explosives of Division 4.1, may only be offered for transportation and transported under conditions approved by the Associate Administrator. However, the design stress limits may not exceed 25 percent of the stress for 0 temper at the maximum design temperature of the cargo tank, as specified in the Aluminum Association's Aluminum Standards and Data (IBR, see 171.7 of this subchapter). Except for a portable tank containing refrigerated liquefied helium, a portable tank shall have an outage of at least two percent below the inlet of the pressure relief device or pressure control valve, under conditions of incipient opening, with the portable tank in a level attitude. 337 Authorizes the use of regulated waste containers manufactured prior to October 1, 2006 to be marked with the alternative shipping name of Regulated medical waste, UN3291 and arrows that deviate as prescribed in 172.312(a)(2) in that they may be black or white. N76 For materials of not more than 25 percent active ingredient by weight, packages consisting of inner metal packagings not greater than 250 mL (8 ounces) capacity each, packed in strong outer packagings together with sufficient absorbent material to completely absorb the liquid contents are authorized and need not conform to the requirements of part 178 of this subchapter. When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. Lead compounds which, when mixed in a ratio of 1:1,000 with 0.07 M (Molar concentration) hydrochloric acid and stirred for one hour at a temperature of 23 C 2 C, exhibit a solubility of 5% or less are not subject to the requirements of this subchapter unless they meet criteria as another hazard class or division. If one of the components, which can be a pure substance or a mixture, is classed as flammable, the chemical under pressure must be classed as flammable in Division 2.1. When such batteries are transported in accordance with 173.185(c), the total lithium content of all lithium metal cells contained in the battery must not exceed 1.5 g and the total capacity of all lithium ion cells contained in the battery must not exceed 10 Wh. The batteries inside the cargo transport unit are not subject to marking or labelling requirements of part 172 subparts D and E of this subchapter. B76 Tank cars constructed before March 16, 2009, must have a test pressure of 20.68 Bar (300 psig) or greater and conform to Class 105S, 112J, 114J or 120S. TP10 A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority, is required. 19 For domestic transportation only, the identification number UN1075 may be used in place of the identification number specified in column (4) of the 172.101 table. PDF Hazard Classifications Used in Hazmat Table, Column 3 Uranium hexafluoride may be classified under this entry only if the conditions of 173.420(a)(4) and (6) and (d) and 173.421(b) and (d) of this subchapter, and, for fissile-excepted material, the conditions of 173.453 of this subchapter are met. In addition to the packaging required in 173.4a, each glass inner packaging must be placed in a sealed plastic bag compatible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner packaging; and. B18 Open steel hoppers or bins are authorized. Lithium ion cells and batteries at a state of charge greater than 30 percent of their rated capacity may only be transported under conditions approved by the Associate Administrator in accordance with the requirements in 49 CFR part 107, subpart H. Guidance and methodology for determining the rated capacity can be found in sub-section 38.3.2.3 of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the subpart E (labeling) requirements of this part when offered for transportation by motor vehicle, rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned in 173.62 of this subchapter, in conformance with the following conditions: a. Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must use the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. For this test, the provisions of paragraphs 16.6.1.2 except letter g, 16.6.1.3.1 to 16.6.1.3.6, 16.6.1.3.7(b) and 16.6.1.3.8 of the UN Manual of Tests and Criteria must be applied. Navigate by entering citations or phrases Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 10.34 Bar (150 psig). 164 Substances must not be transported under this entry unless approved by the Associate Administrator on the basis of the results of appropriate tests according to Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). When a specific portable tank instruction is specified by a T Code in Column (7) of the 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if: (A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified); (B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified); (C) The alternative portable tank has a pressure relief device as specified in the T Code. When phlegmatized with water and inorganic inert material, the content of urea nitrate must not exceed 75 percent by mass and the mixture should not be capable of being detonated by test 1(a)(i) or test 1(a)(ii) in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). Special Provision Letter Codes Used in Hazmat Table, Column 7 Column 7 uses eight letter codes. In addition to the provisions applicable to the transport of Division 6.1 substances, the provisions of 173.421(c) and 173.443(a) of this subchapter apply. Example: Yes, I would like to receive emails from Daniels Training Services. 167 These storage systems must always be considered as containing hydrogen. If you have questions or comments regarding a published document please Packaging Authorizations (Column 8) For UN identification numbers 3531, 3532, 3533, and 3534, IBCs must be designed and constructed to permit the release of gas or vapor to prevent a build-up of pressure that could rupture the IBCs in the event of loss of stabilization. PDF 4756 Federal Register /Vol. 88, No. 16/Wednesday, January 25, 2023 TP47 The 2.5 year internal examination may be waived or substituted by other test methods or inspection procedures specified by the competent authority or its authorized body, provided that the portable tank is dedicated to the transport of the organometallic substances to which this tank special provision is assigned. citations and headings 441 For marine pollutants transported under UN3077, Environmentally hazardous substance, solid, n.o.s. or UN3082, Environmentally hazardous substance, liquid, n.o.s. and for purposes of shipping paper and package marking requirements, the technical name used in association with the basic description may be a proper shipping name listed in the 172.101 Hazardous Material Table; provided that the name chosen is not also an entry that includes n.o.s. as a part of the name or one that has a G in column (1) of the table. result, it may not include the most recent changes applied to the CFR. will bring you to those results. The requirements of 173.24(g)(1) and 173.27(c) do not apply. N74 Packages consisting of tightly closed inner containers of glass, earthenware, metal or polyethylene, capacity not over 0.5 kg (1.1 pounds) securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, not over 15 kg (33 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter. See Batteries, dry, sealed, n.o.s. in the 172.101 Hazardous Materials Table (HMT) of this part for transportation requirements for nickel-metal hydride batteries transported by other modes and for nickel-metal hydride button cells or nickel-metal hydride cells or batteries packed with or contained in battery-powered devices transported by vessel. 365 For manufactured instruments and articles containing mercury, see UN3506. N37 This material may be shipped in an integrally-lined fiber drum (1G) which meets the general packaging requirements of subpart B of part 173 of this subchapter, the requirements of part 178 of this subchapter at the packing group assigned for the material and to any other special provisions of column 7 of the 172.101 table. a. A 25 mm (1 inch) woven lining of asbestos or other approved material must be placed between the bolster slabbing and the bottom of the tank. The article, machinery, or apparatus, if unpackaged, or the packaging in which it is contained shall be marked Dangerous goods in articles or Dangerous goods in machinery or Dangerous goods in apparatus as appropriate, with the identification number UN3363. However, sediments remaining in the tank that meet the definition for a hazardous material are subject to the applicable regulations of this subchapter. Special provisions contain packaging provisions, prohibitions, exceptions from requirements for particular quantities or forms of materials and requirements or prohibitions applicable to specific modes of transportation, as follows: (1) A code consisting only of numbers (for example, 11) is multi-modal in application and may apply to bulk and non-bulk packagings. (3) A code containing the letter B refers to a special provision that applies only to bulk packaging requirements. A combination packaging consisting of a 4G fiberboard box with inner receptacles of glass or earthenware; b. The manufacturer must provide such information to a representative of the Department upon request. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. No outage is required for helium. The means of protection must be approved by the approval agency designated to approve the portable tank in accordance with the procedures in part 107, subpart E, of this subchapter. 172-29, 41 FR 15996, Apr. When there is an entry in this column, refer to Section 172.102 of the federal regulations for specific information. A61 a. We recommend you directly contact the agency responsible for the content in question. Interpretation Response | PHMSA - Pipeline and Hazardous Materials 44 The formulation must be prepared so that it remains homogenous and does not separate during transport. 33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. 134 This entry applies only to vehicles powered by wet batteries, sodium batteries, lithium metal batteries or lithium ion batteries, and equipment powered by wet batteries or sodium batteries that are transported with these batteries installed. 159 This material must be protected from direct sunshine and kept in a cool, well-ventilated place away from sources of heat. A105 a. The chemical under pressure must be classed based on the hazard characteristics of the components in the propellant; the liquid; or the solid. e. A description to which special provision 170 or TP7 is assigned in Column 7 of the 172.101 Hazardous Materials Table, and therefore requires air to be eliminated from the package vapor space by nitrogen or other means, must not be offered for transportation under this description. e. Transport in accordance with this special provision must be noted on the shipping paper. Each For Federal Register citations affecting 172.102, see the List of CFR Sections Affected, which appears in the Finding Aids section of the printed volume and at www.govinfo.gov. b. B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized. Learn more about the eCFR, its status, and the editorial process. A210 This substance is forbidden for transport by air. US Department of Transportation (DOT) Pipeline Hazardous Materials Safety b. The eCFR is displayed with paragraphs split and indented to follow The manufacturer must apply procedures to ensure that articles produced in series are made of good quality, conform to the design type and are able to meet the requirements in (a). that, for example, are used for medical, analytical, diagnostic, testing, or repair purposes. Liquefied compressed gases are assigned to portable tank instruction T50. An installed inflation cylinder that requires recharging must be filled in accordance with 173.301(l). These provisions apply only to non-bulk packagings: N3 Glass inner packagings are permitted in combination or composite packagings only if the hazardous material is free from hydrofluoric acid. Microsoft Edge, Google Chrome, Mozilla Firefox, or Safari. A portable tank may be offered for transport after the date of expiry of the last lining inspection for a period not to exceed three months for purposes of performing the next required test or inspection, after emptying but before cleaning. B59 Water-tight, sift-proof, closed-top, metal-covered hopper cars are also authorized provided that the lading is covered with a nitrogen blanket. During transport, it must be protected from direct sunshine and stored (or kept) in a cool and well-ventilated place, away from all sources of heat. Sealed packets and articles containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed onto a solid material are not subject to this subchapter provided there is no free liquid in the packet or article. The requirements of 172.203(m) and 172.505 of this subchapter do not apply. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. Packagings must be sift-proof, prevent liquid water from reaching the hazardous material, and be provided with sufficient venting to preclude dangerous accumulation of flammable, corrosive, or toxic gaseous emissions such as methane, hydrogen, and ammonia. Limited propagation means that if one booster near the center of the package is exploded, the aggregate weight of explosives, excluding ignition and delay charges, in this and all additional boosters in the outside packaging that explode may not exceed 25 g. 116 Fuzes, detonating may be classed in Division 1.4 if the fuzes do not contain more than 25 g of explosive per fuze and are made and packaged so that they will not cause functioning of other fuzes, explosives or other explosive devices if one of the fuzes detonates in a shipping packaging or in adjacent packages. The tank car specification may be marked to indicate a test pressure of 13.79 Bar (200 psig). 421 This entry will no longer be effective on January 2, 2023, unless we terminate it earlier or extend it beyond that date by notice of a final rule in the Federal Register. 49 U.S.C. 368 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN3507 or UN2978. What does the sign in column 1 of the hazardous materials Table mean Specifically, you seek clarification on the implementation of special provision IP15which is listed in Column 7 of the 172.101 Hazardous Materials Table (HMT)as it applies when this material is packaged in a composite intermediate bulk container (IBC) with a rigid inner receptacle. The capacity of each drum must not exceed 220 L (58 gallons). B35 Tank cars containing hydrogen cyanide may be alternatively marked Hydrocyanic acid, liquefied if otherwise conforming to marking requirements in subpart D of this part. This entry does not apply to life saving appliances described in 173.219 (UN2990 and UN3072). 49 CFR -172.101 Hazardous Materials Table info - MaselliWeb 332 Magnesium nitrate hexahydrate is not subject to the requirements of this subchapter. In addition, the portable tank must be designed so that internal surfaces may be effectively cleaned and passivated. (ii) The following is a list of the portable tank special provisions: TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. 325 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. (TOY CAPS) - HANDLE CAREFULLY OR TOY CAPS - HANDLE CAREFULLY; and. Formulations not meeting these criteria must be transported under the provisions applicable to the appropriate entry in the Organic Peroxide Table in 173.225 of this subchapter. Testing must be conducted on at least three packages as prepared for transport. Each tank must be equipped with pressure relief devices conforming to the following requirements: 1 Total venting capacity in standard cubic feet hour (S.C.F.H.) When a placard is displayed, the placard must be the placard shown in 172.560. Where the subsidiary hazard material is Forbidden in column (9A) or (9B) of the 172.101 Table, the radioactive material may only be offered for transportation and transported by aircraft under conditions approved by the Associate Administrator. 155 Fish meal, fish scrap and krill meal may not be transported if the temperature at the time of loading either exceeds 35 C (95 F), or exceeds 5 C (41 F) above the ambient temperature, whichever is higher. Based on the volatility class determined by using ASTM D 439 and the Reid vapor pressure (RVP) of the particular gasoline, the maximum lading pressure and maximum ambient temperature permitted during the loading of gasoline may not exceed that listed in Table I. TP29 A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the hazardous materials, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Except as otherwise provided in this subchapter, these special provisions do not apply to UN portable tanks or IBCs: B1 If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the bulk packaging requirements of 173.241 of this subchapter are applicable. N79 Packages consisting of tightly closed metal inner packagings not over 0.5 kg (1.1 pounds) capacity each, packed in outer wooden or fiberboard boxes, or wooden barrels, are authorized and need not conform to the requirements of part 178 of this subchapter.